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现代矿业 ›› 2022, Vol. 38 ›› Issue (07): 162-.

• 矿物加工工程 • 上一篇    下一篇

月桂酸对煤气化细渣浮选的促进作用研究

程延化   

  1. 晋能控股煤业集团晋城煤炭事业部煤炭加工利用分公司寺河选煤厂
  • 出版日期:2022-07-25 发布日期:2023-06-09

Study on the Promotion Effect of Lauric Acid on Flotation of Coal Gasification Fine Slag

CHENG Yanhua   

  1. Sihe Coal Preparation Plant,Jincheng Coal Division Coal Processing and Utilization Branch,Jinneng Holding Coal Industry Group
  • Online:2022-07-25 Published:2023-06-09

摘要: 为了分离煤气化细渣中的残碳与灰质,针对煤气化细渣表面存在大量含氧官能团和 孔隙,传统的烃类捕收剂难以回收其中的残碳等问题,进行了以月桂酸和煤油为复配药剂的捕收 剂用量浮选试验。试验结果表明:少量的煤油加入月桂酸后作为捕收剂在提高精矿产率与可燃体 回收率的同时,可降低其尾矿烧失量;当复配药剂用量提高到16 kg/t时,尾矿烧失量降低到8 %以 下,可燃体回收率超过90 %;月桂酸的加入可以加大煤油在水中的分散作用,从而增加残碳颗粒 与捕收剂液滴的接触面积,两者的协同作用可以提高残碳颗粒的疏水性和可浮性,并且通过接触 角结果验证了使用不同捕收剂进行浮选试验时得到的精矿产率与可浮性的关系。借助BET 测试 与发热量测试分析浮选产品孔隙结构参数与热值,为产品再利用提供了理论支持。

关键词: 煤气化细渣, 月桂酸, 烧失量, 浮选

Abstract: In order to separate the residual carbon and ash in the coal gasification fine slag,the flota⁃ tion test of collector dosage with lauric acid and kerosene as compound reagent was carried out aiming at the problems that there are a large number of oxygen-containing functional groups and pores on the surface of coal gasification fine slag and the traditional hydrocarbon collector is difficult to recover the residual car⁃ bon. The experimental results show that the addition of a small amount of kerosene into lauric acid as col⁃ lector can improve the concentrate yield and combustible recovery rate,and reduce the burning loss of tail⁃ ings. When the dosage of compound reagent is increased to 16 kg/t,the burning loss of tailings is reduced to less than 8%,and the combustible recovery is more than 90%. The addition of lauric acid can increase the dispersion of kerosene in water,thereby increasing the contact area between residual carbon particles and collector droplets. The synergistic effect of lauric acid and collector droplets can improve the hydropho⁃ bicity and floatability of residual carbon particles. The contact angle test results verify the relationship be⁃ tween concentrate yield and floatability when using different collectors for flotation tests. The pore structure parameters and calorific value of flotation products were analyzed by BET test and calorific value test, which provided theoretical support for product reuse.

Key words: coal gasification fine slag, lauric acid, burning loss, flotation