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现代矿业 ›› 2022, Vol. 38 ›› Issue (08): 154-.

• 矿物加工工程 • 上一篇    下一篇

某拜耳法赤泥直接还原选铁试验

李家林   

  1. 长沙矿冶研究院有限责任公司
  • 出版日期:2022-08-25 发布日期:2023-06-07
  • 基金资助:
    国家重点研发计划项目(编号:2020YFC1909802)。

Experiments of Iron Selection in a Red Mud from Bayer Process by Direct Reduction

LI Jialin   

  1. Changsha Research Institute of Mining and Metallurgy Co.,Ltd.
  • Online:2022-08-25 Published:2023-06-07

摘要: 广西某氧化铝厂拜耳法赤泥铁品位为26.06%、Al2O3含量为17.53%、TiO2含量为5.32%, 有害成分磷、硫含量较低;试样中的铁主要以赤(褐)铁矿的形式存在,分布率达96.85%,主要铁矿 物为赤铁矿,其次为褐铁矿;钛矿物以钙钛矿为主,脉石矿物以水铝硅酸钙、钙霞石、氧硅钛钠石 和方解石为主。为高效回收其中的铁,采用直接还原—磨矿—弱磁选工艺进行了选矿试验。结 果表明,试样在煤粉用量为30%、还原温度为1 100 ℃、还原时间为120 min,熟料磨矿细度为-0.045 mm86.75%、弱磁选磁场强度为103.50 kA/m 条件下,获得了产率为23.17%、TFe 品位为88.60%、回 收率为78.77%的铁粉,较好地实现了其中铁的回收。

关键词: 赤泥, 直接还原, 磨矿, 磁选

Abstract: The content of Fe,Al2O3 and TiO2 in the Bayer Red Mud samples from a Guangxi Alumi⁃ num Oxide Factory were 26.06%,17.53% and 5.32% respectively,and harmful substances phosphorus and sulfur were very low. The iron mainly exists in the form of hematite and limonite with the distribution rate of 96.85%. The main iron mineral is hematite,followed by limonite. The titanium mineral mainly ex⁃ ists in the form of perovskite,and gangue minerals are mainly in the form of calcium aluminosilicate hy⁃ drate,cancrinite,natisite and calcite. In order to recover the iron from red mud samples efficiently,the beneficiation experiments of direct reduction,grinding and low intensity magnetic separation process were carried out. The results showed that the direct reduction iron products with yield of 23.17%,TFe grade of 88.60% and iron recovery rate of 78.77% could be obtained under the conditions of anthracite addition of 30%,reduction temperature of 1 100 ℃,reduction time of 120 min,grinding fineness of -0.045 mm ac⁃ counting for 86.75% and magnetic field intensity of 103.50 kA/m,which indicated the better recovery ef⁃ fect of iron.

Key words: red mud, direct reduction, grinding, magnetic separation