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现代矿业 ›› 2023, Vol. 39 ›› Issue (03): 149-153.

• 矿物加工工程 • 上一篇    下一篇

云南麻栗坡祖母绿矿物学及谱学特征研究

赵栩锐1 沙鑫1,2,3 尹悦1 赵红英1 张闪硕1 谢爱香1   

  1. 1. 桂林理工大学地球科学学院;2. 桂林理工大学珠宝检测中心;3. 广西隐伏金属矿产勘查重点实验室
  • 出版日期:2023-03-25 发布日期:2023-05-05
  • 基金资助:
    广西科技计划项目(编号:桂科AD19110048);广西自然科学基金项目(编号:2022GXNSFBA035595);桂林理工大学科研启动基金项目(编号:GUTQDJJ2017101)

Mineralogical and Spectral Characterization of Emerald from Malipo,Yunnan Province

ZHAO Xurui1 SHA Xin1,2,3 YIN Yue1 ZHAO Hongying1 ZHANG Shanshuo1 XIE Aixiang1   

  1. 1. School of Earth Sciences,Guilin University of Technology;2. Jewelry Testing Center,Guilin Universi⁃ ty of Technology;3. Guangxi Key Laboratory of Hidden Metallic Ore Deposits Exploration
  • Online:2023-03-25 Published:2023-05-05

摘要: 云南麻栗坡祖母绿矿床赋存于老君山变质核杂岩中,是我国目前发现最具经济价值的 祖母绿矿床。为研究该矿床所产祖母绿的矿物学特征,运用电子探针、红外光谱及拉曼光谱技术,分 析其矿物化学成分及光谱学特征。结果表明,云南麻栗坡祖母绿的主要成分为SiO2、Al2O3和BeO, V2O5的含量较高,Cr2O3、K2O 和Na2O 含量均较低;红外光谱主要吸收峰位于1 167、1 050、991、844、 773、710、614、567、504、480 cm-1附近,与澳大利亚孟席斯祖母绿的红外光谱特征基本一致,但与赞比 亚及新疆祖母绿差异较大;4 个产地祖母绿的拉曼谱峰总体趋势较为一致,均表现出绿柱石的拉曼光 谱特征,但它们也存在诸多不同,可能是成矿环境差异的宏观表现,可作为产地的鉴别依据。

关键词: 麻栗坡, 祖母绿, 矿物学, 光谱学, 电子探针

Abstract: Malipo emerald deposit occurs in Laojunshan metamorphic core complex. It is the most economically valuable emerald deposit in China. In order to study the mineralogical characteristics of emeralds produced in this deposit,electron probe,infrared spectrum and Raman spectrum were used to analyze the mineral chemical composition and spectral characteristics. The results show that the main components of Malipo emerald are SiO2,Al2O3 and BeO.The results showed that the main components of emeralds from Malipo were SiO2,Al2O3 and BeO,and the contents of V2O5 were high,while the contents of Cr2O3,K2O and Na2O were low. The main absorption peaks of infrared spectrum are located at 1 167,1050,991,844,773, 710,614,567,504,and 480 cm-1. Their infrared spectral characteristics are basically consistent with Australian Menzies emeralds,but they are different from Zambian and Xinjiang. The Raman spectrum peaks of emeralds from the four localities have the same general trend,and show the Raman spectrum characteristics of beryl. However,there are many differences between them,which may be the macroscopic manifestation of metallogenic environment differences,and can be used as the basis for identification of origin.

Key words: Malipo, emerald, mineralogy, spectroscopy, electron probe