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现代矿业 ›› 2023, Vol. 39 ›› Issue (02): 219-222.

• 安全·环保 • 上一篇    下一篇

破氰—沉氰联合工艺处理含氰尾矿浆试验研究

费运良 郭雪婷 王莹 降向正 吴奇   

  1. 长春黄金研究院有限公司
  • 出版日期:2023-02-25 发布日期:2023-05-11

Experimental Study on Cyanide-containing Tailing Pulp Treatment by Cyanide Breaking and Cyanide Precipitation Combined Process

FEI Yunliang GUO Xueting WANG Ying JIANG Xiangzheng WU Qi   

  1. Changchun Gold Research Institute Co.,Ltd.
  • Online:2023-02-25 Published:2023-05-11

摘要: 某黄金公司全泥氰化尾矿浆液相总氰化物含量为805.58 mg/L,以(亚)铁氰络合离子 形式为主,将原矿浆浓密至55% 情况下进行毒性浸出试验,浸出液总氰化物含量高达51.7 mg/L。 为实现无害化处理,进行了一系列试验。结果表明,单一破氰工艺难以有效去除络合氰化物,破 氰—沉氰联合工艺可以有效去除络合氰化物,但难以达到目标要求;向经过压滤/浓密—清水调浆 处理的全泥氰化尾矿浆中加入3 g/L的破氰药剂CG105-A和2.5 g/L的沉氰药剂CG105-B即可满足 氰化物处理目标要求。

关键词: 含氰尾矿浆, 氰渣, 因科法, 双氧水法, 破氰, 沉氰

Abstract: The total cyanide content of the full-slime cyanide tailings slurry of a gold company was 805.58 mg/L,mainly in the form of (ferric) ferricyanide complex ions. The toxicity leaching test was carried out when the raw ore pulp was thickened to concentration of 55%,and the total cyanide content of the leaching solution was as high as 51.7 mg/L. In order to achieve harmless treatment,a series of experiments were carried out. The results showed that it is difficult to effectively remove complex cyanide by a single cyanide breaking process,and the combined cyanide breaking and precipitation cyanide process can effectively remove complex cyanide,but it is difficult to achieve the target requirements. Adding 3 g/L of cyanide breaking agent CG105-A and 2.5 g/L of cyanide precipitation agent CG105-B to the cyanide tailings slurry can meet the target requirements of cyanide treatment.

Key words: cyanide-containing tailing pulp, cyanide residue, INCO method, hydrogen peroxide method, cyanide breaking, cyanide precipitation