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现代矿业 ›› 2022, Vol. 38 ›› Issue (08): 223-.

• 安全·环保 • 上一篇    下一篇

工农固废协同稳定化多重金属废矿渣研究

苏建1,2 李小明1 华绍广3 尹娟2 廖春雨2 宋海农2   

  1. 1. 湖南大学环境科学与工程学院;2. 广西博世科环保科技股份有限公司; 3. 中钢集团马鞍山矿山研究总院股份有限公司
  • 出版日期:2022-08-25 发布日期:2023-06-07
  • 基金资助:
    国家重点研发计划项目(编号:2019YFC1803500)。

Research on Stabilization of Multiple High Metal Crap Slag with Industrial-agricultural Solid Waste Collaborative Action

SU Jian1,2 LI Xiaoming1 HUA Shaoguang3 YIN Juan2 LIAO Chunyu2 SONG Hainong2   

  1. 1. College of Environmental Science and Engineering,Hunan University; 2. Guangxi Bossco Environmen⁃ tal Protection Technology Co.,Ltd.; 3. Sinosteel Maanshan General Institute of Mining Research Co.,Ltd.
  • Online:2022-08-25 Published:2023-06-07

摘要: 为给工农固废用于重金属废渣/污染土稳定化修复提供理论与技术依据,研究了工业 固废钢渣、脱硫石膏,农业固废甘蔗渣、鸡粪对冶炼废渣中重金属的同步稳定化效果。在反应层固 废与废矿渣混合比(体积比)为1∶9,材料脱硫石膏、钢渣、甘蔗渣、畜禽粪便的配比为1∶1∶6∶12条件 下,研究了废矿渣中As、Pb、Zn 的浸出毒性在0~360 d的变化情况,同时分析了工农固废协同情况 下反应层微生物群落360 d的变化。结果表明,废矿渣中As、Pb、Zn 的360 d 浸出毒性分别降低了 99.8%、100%(未检出)和86.5%,达到地表水Ⅲ类水质标准;从180~360 d的微生物群落数据看,共 有OTU占比逐渐降低,阶段降幅分别为22.3个百分点和11.8个百分点;180 d和360 d的门、纲水平 高丰度物种相对稳定,γ-变形菌纲、α-变形菌纲、放线菌纲、拟杆菌纲和第四门纲、绿湾菌纲、杆菌 纲、酸杆菌纲丰度较高,协同稳定化主要诱导以上菌群的丰度变化,进而影响重金属形态与毒性。

关键词: 冶金固废, 农业固废, 重金属, 稳定化, 微生物

Abstract: In order to provide theoretical and technical basis for heavy metal waste slag or contaminat⁃ ed soil stabilization remediation by using industrial and agricultural solid waste,the synchronous stabiliza⁃ tion effect of industrial solid waste steel slag and desulfurization gypsum,agricultural solid waste bagasse and chicken manure on heavy metals in metallurgical waste residue was studied. Under the conditions of the mixing ratio(volume ratio)of solid waste and waste slag in the reaction layer was 1∶9,and the ratio of material desulfurization gypsum,steel slag,bagasse,poultry manure was 1∶1∶6∶12,the change of leach⁃ ing toxicity on As,Pb and Zn in the waste slag by 360 days was tested. At the same time,the microbial com⁃ munity of the reaction layer was analyzed for 360 days under the condition of metallurgy-agriculture solid waste synergy. The results showed that the leaching toxicity of As,Pb and Zn was respectively reduced by 99.8%,100%(NG)and 86.5%,and the leaching water was reached the surface water quality standard of Class III. From the microbial community data of 180 d and 360 d,the proportion of shared OTU were gradu⁃ ally decreased by 22.3 percentage points and 11.8 percentage points respectively.The high-abundance spe⁃ cies were relatively stable at phylum and class level in 180 d and 360 d,in which class as Gammaproteobac⁃ teria,Alphaproteobacteria,Actinobacteria,Bacteroidia,Fourth phylum chloroflexia,Bacilli,Gemmatimonade⁃ tes are higher than others,so it is considered that the multi-layer covering mainly induces changes in the abundance of the above flora,which in turn affects the morphology and toxicity of heavy metals.

Key words: metallurgical solid waste, agriculture solid waste, heavy metal, stabilization, microorgan? isms