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现代矿业 ›› 2026, Vol. 42 ›› Issue (01): 229-232,237.

• 安全·环保 • 上一篇    下一篇

某企业选矿外排废水自行监测现状分析

王玉洁1 尚毅林2   

  1. 1. 南京宝地梅山产城发展有限公司矿业分公司;2. 南京市生态环境保护科学研究院
  • 出版日期:2026-01-25 发布日期:2026-02-05

Analysis on the Current Situation of Self-monitoring of Wastewater Discharged from Mineral Processing in an Enterprise

  1. 1. Mining Branch,Nanjing Baodi Meishan Industrial City Development Co.,Ltd.; 2. Nanjing Research Institute of Ecological Environmental Protection
  • Online:2026-01-25 Published:2026-02-05

摘要: 为了掌握某企业选矿外排废水主要污染物的排放规律与达标稳定性,为排污企业精 准治污与生态环境部门依证监管提供科学依据,针对铁矿采选行业废水水量大、成分复杂的问题, 对某企业 2022—2024 年选矿环水排口监测数据进行分析,重点评估 COD、氨氮、总磷、总氮 4 项指 标的排放规律以及水质的感官特征。研究结果表明:监测期间 COD、氨氮、总磷的排放浓度均值能 满足现行排放标准要求,但 COD 指标存在间歇性浓度峰值,最高浓度达 59 mg/L,其排放稳定性有 待加强;总氮的排放浓度区间为 0.38~15.00 mg/L,整体浓度水平偏高,接近排放限值的样本数量占 总样本的 19.44%,存在较大的超标风险。进一步分析发现,该外排废水呈现出显著的低碳氮比特 征,C/N 值低于 5 的样本占比高达 58.33%,这一水质特性严重制约了传统生物脱氮工艺的效率;除 此之外,废水长期呈现红褐色且浑浊的状态,表明存在大量的悬浮物颗粒。基于以上结果可知,该 企业外排废水虽部分指标达标,但总氮超标风险突出且生物脱氮潜力受限,亟需开展废水中总氮 的精准溯源,并系统评估废水的可生化性,为废水处理工艺的定向优化与污染物的长期稳定达标 排放提供坚实的理论依据和数据支撑。

关键词: 选矿废水, 自行监测, 低碳氮比, 溯源解析

Abstract: In order to grasp the emission law and standard stability of the main pollutants in the wastewater discharged of mineral processing from a certain enterprise,and provide a scientific basis for the accurate pollution control of the sewage enterprises and the supervision of the ecological environment de⁃ partment according to the evidence,aiming at the problems of large amount of wastewater and complex com⁃ position in the iron ore mining and dressing industry,the monitoring data of the mineral processing circu⁃ lating water discharge of a certain enterprise in 2022—2024 are analyzed,focusing on the evaluation of the emission law of COD,ammonia nitrogen,total phosphorus and total nitrogen and the sensory character⁃ istics of water quality.The results show that the average emission concentrations of COD,ammonia nitrogen and total phosphorus during the monitoring period can meet the requirements of the current emission stan⁃ dards,but there is an intermittent concentration peak of COD index,the highest concentration is 59 mg/L, and its emission stability needs to be strengthened. The emission concentration range of total nitrogen is 0.38~15.00 mg/L,and the overall concentration level is high. The number of samples close to the emis⁃ sion limit accounts for 19.44% of the total samples,and there is a large risk of exceeding the standard.Fur⁃ ther analysis shows that the discharged wastewater shows significant low carbon-nitrogen ratio characteris⁃ tics,and the proportion of samples with C/N value less than 5 is as high as 58.33%. This water quality characteristic seriously restricts the efficiency of traditional biological nitrogen removal process.In addi⁃tion,the wastewater has long been reddish brown and turbid,indicating the presence of a large number of suspended particles.Based on the above results,although some indexes of the discharged wastewater from the enterprise meet the standards,the risk of total nitrogen exceeding the standard is prominent and the po⁃ tential of biological nitrogen removal is limited. It is urgent to carry out accurate traceability of total nitro⁃ gen in wastewater and systematically evaluate the biodegradability of wastewater,so as to provide a solid theoretical basis and data support for the directional optimization of wastewater treatment process and the long-term stable discharge of pollutants.

Key words: beneficiation wastewater, self-monitoring, low carbon nitrogen ratio, traceability analysis