欢迎访问《现代矿业》杂志官方网站,今天是 分享到:
×

扫码分享

现代矿业 ›› 2023, Vol. 39 ›› Issue (03): 187-191.

• 矿物加工工程 • 上一篇    下一篇

高级氧化技术在硫化矿浮选中的应用

郁刘发   

  1. 国投新疆罗布泊钾盐有限责任公司
  • 出版日期:2023-03-25 发布日期:2023-05-05

Application of Advanced Oxidation Processes on the Flotation of Sulphide Ore

YU Liufa   

  1. SDIC Xinjiang Lop Nur Potash Co.,Ltd.
  • Online:2023-03-25 Published:2023-05-05

摘要: 为了促进高级氧化技术在硫化矿浮选中的运用与推广,针对现阶段可用于开采的硫 化矿多为贫矿且伴生情况复杂、易分选硫化矿富矿逐渐减少、浮选分离效率低下、浮选精矿品位低 和回收率不理想等问题,综述了高级氧化技术臭氧氧化、芬顿氧化和电化学催化氧化的作用机理 及3 种氧化技术在硫化矿分选过程中的应用现状及作用机制。高级氧化技术因可生成强氧化性 羟基自由基、硫酸根自由基及超氧自由基等,使硫化矿表面因氧化产生新物质附着而改变矿物表 面亲疏水性,并影响矿物与捕收剂之间的作用。通过对现阶段高级氧化技术在硫化矿浮选中的运 用进行总结,发现通过控制氧化过程从而调控矿物表面性质,可作为实现硫化矿中有用矿物与脉 石矿物分离的新思路。

关键词: 硫化矿, 浮选, 表面氧化, 高级氧化, 可浮性

Abstract: In order to promote the application and promotion of advanced oxidation technology in sulfide ore flotation,in view of the problems that most of the sulfide ore that can be used for mining at this stage are poor and complicated,the rich ore of easy-to-separate sulfide ore is gradually reduced,the flotation separation efficiency is low,the flotation concentrate grade is low and the recovery rate is not ideal, the mechanism of ozone oxidation,Fenton oxidation and electrochemical catalytic oxidation of advanced oxidation technology and the application status and mechanism of three oxidation technologies in sulfide ore separation process are reviewed. Advanced oxidation technology can produce strong oxidizing hydroxyl radicals,sulfate radicals and superoxide radicals,so that the surface of sulfide ore can produce new substances due to oxidation,which can change the hydrophilicity and hydrophobicity of mineral surface and affect the interaction between minerals and collectors. By summarizing the application of advanced oxidation technology in sulfide ore flotation at present,it is found that controlling the oxidation process to regulate the surface properties of minerals can be used as a new idea to realize the separation of useful minerals and gangue minerals in sulfide ore.

Key words: sulphide ore, flotation, surface oxidation, advanced oxidation, floatability