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现代矿业 ›› 2026, Vol. 42 ›› Issue (09): 135-139,187.

• 矿物加工工程 • 上一篇    下一篇

西藏某含铜废石生物浸出试验

刘建伟 逄军武 周永程 付海泽 张建兴 樊海洋   

  1. 西藏华泰龙矿业开发有限公司
  • 出版日期:2026-09-25 发布日期:2026-10-13

Bioleaching Test of a Copper-containing Waste Rock in Xizang

LIU Jianwei PANG Junwu ZHOU Yongcheng FU Haize ZHANG Jianxing FAN Haiyang   

  1. Xizang Huatailong Mining Development Co.,Ltd.
  • Online:2026-09-25 Published:2026-10-13

摘要: 为了实现西藏某含铜废石的资源化利用,并同步治理矿区酸性废水,通过工艺矿物 学分析,明确了该废石的矿物学特征,经菌种驯化、单因素试验,优化了生物浸出最佳工艺参数,同 时开展了浸渣物相分析,探究了有价金属浸出残留的原因。试验结果表明:该含铜废石铜品位 0.18%,锌品位 0.22%,主要含铜矿物为斑铜矿(0.16%)和辉铜矿(蓝辉铜矿 0.04%),脉石矿物中的 方解石含量达 17.47%,导致酸耗高达 426 kg/t;经 2 轮带矿驯化,筛选出了专用高效浸矿菌 JC(嗜温 菌)和 MXG(中等嗜热菌);生物浸出最佳工艺参数为初始 pH=2.00,采用 JC 嗜温菌(30 ℃),接种量 10%,矿浆浓度 5%,磨矿细度-0.038 mm86.32%,浸出 40 d,该条件下的铜浸出率 92.84%,锌浸出率 81.76%;浸渣中的铜主要残留于原生硫化铜相,锌主要因闪锌矿嵌布特征及硅酸盐包裹导致浸出 不完全,为该含铜废石的资源化利用及矿区酸性废水综合治理提供了技术支撑。

关键词: 含铜废石, 工艺矿物学, 生物浸出, 菌种驯化, 资源化利用

Abstract: In order to realize the resource utilization of a copper-containing waste rock in Xizang and simultaneously treat the acid wastewater in the mining area,the mineralogical characteristics of the waste rock are clarified through process mineralogy analysis. The optimum process parameters of bioleach⁃ ing are optimized by strain domestication and single factor test. At the same time,the phase analysis of the leaching residue is carried out to explore the reasons for the leaching residue of valuable metals.The test re⁃ sults show that the copper grade of the copper-containing waste rock is 0.18%,the zinc grade is 0.22%, the main copper-containing minerals are bornite(0.16%)and chalcocite(0.04%),and the calcite con⁃ tent in the gangue mineral reaches 17.47%,resulting in an acid consumption of up to 426 kg/t. After two rounds of domestication with ore,special high-efficiency leaching bacteria JC(thermophilic bacteria) and MXG(moderately thermophilic bacteria)are screened out.The optimum technological parameters of bioleaching are as follows: initial pH=2.00,JC thermophilic bacteria(30 ℃),inoculation amount 10%, pulp concentration 5%,grinding fineness - 0.038 mm 86.32%,leaching time 40 d. Under these condi⁃ tions,the copper leaching rate is 92.84% and the zinc leaching rate is 81.76%.The copper in the leaching residue mainly remains in the primary copper sulfide phase,and the zinc is mainly leached incompletely due to the dissemination characteristics of sphalerite and silicate encapsulation,which provides technical support for the resource utilization of the copper-containing waste rock and the comprehensive treatment of acid wastewater in the mining area.

Key words: copper-containing waste rock, process mineralogy, bioleaching, strain domestication, resource utilization