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现代矿业 ›› 2026, Vol. 42 ›› Issue (03): 110-113,138.

• 矿物加工工程 • 上一篇    下一篇

某水淬型含钛高炉渣制备低钙镁富钛料试验

姜文杰   

  1. 四川省钒钛产业投资发展有限公司
  • 出版日期:2026-03-25 发布日期:2026-04-09

Experiment on Preparation of Low Calcium Magnesium Titanium-rich Material by Water Quenching Titanium-bearing Blast Furnace Slag

JIANG Wenjie   

  1. Sichuan Vanadium Titanium Industry Investment and Development Co.,Ltd.
  • Online:2026-03-25 Published:2026-04-09

摘要: 为实现某含钛高炉渣中钛资源的高效回收利用,采用硝酸加压浸出工艺,在硝酸用 量 2.3 M(M 为高炉渣质量,硝酸浓度 60%)、浸出液固比 3∶1、浸出温度 150 ℃、浸出时间 1.5 h 的条 件下,高炉渣中钙、镁、铝浸出率分别为 98.10%、97.97% 和 95.58%,可获得 TiO2、SiO2含量分别为 42.01% 和 44.81% 的浸出渣;浸出渣采用常压碱浸工艺,在氢氧化钠用量 0.4 N(N 为加压酸浸渣质 量)、浸出温度 40 ℃、浸出时间 1.5 h、浸出液固比 3∶1 的最佳反应条件下,硅浸出率为 95.20%,钛损 失率为 0.56%。试验结果表明:采用硝酸加压浸出—常压碱浸脱硅工艺制备低钙镁富钛料,最终得 到了 TiO2含量 85.50%、CaO 含量 0.08%、MgO 含量 0.11%、SiO2含量 3.12% 的富钛料,产品质量符合 相关行业标准,为含钛高炉渣的资源化利用提供了新的路径。

关键词: 含钛高炉渣, 湿法提钛, 硝酸浸出, 碱浸, 富钛料

Abstract: In order to realize the efficient recovery and utilization of titanium resources in a titanium�bearing blast furnace slag,nitric acid pressure leaching process is adopted. Under the conditions of nitric acid dosage of 2.3 M(M is the mass of blast furnace slag,nitric acid concentration of 60%),leaching liq‐ uid-solid ratio of 3∶1,leaching temperature of 150 ℃ and leaching time of 1.5 h,the leaching rates of cal‐ cium,magnesium and aluminum in blast furnace slag are 98.10%,97.97% and 95.58%,respectively, and the leaching slag with TiO2 and SiO2 contents of 42.01% and 44.81% are obtained.The leaching resi‐ due is subjected to atmospheric alkali leaching process. Under the optimum reaction conditions of sodium hydroxide dosage 0.4 N(N is the mass of pressurized acid leaching residue),leaching temperature 40 ℃, leaching time 1.5 h,and leaching liquid-solid ratio 3∶1,the leaching rate of silicon is 95.20%,and the loss rate of titanium is 0.56%.The results show that the low calcium and magnesium titanium-rich material is prepared by nitric acid pressure leaching-atmospheric alkali leaching desilication process. Finally,the titanium-rich material with TiO2 content of 85.50%,CaO content of 0.08%,MgO content of 0.11% and SiO2 content of 3.12% is obtained. The product quality meets the relevant industry standards,which pro‐ vides a new path for the resource utilization of titanium-containing blast furnace slag.

Key words: titanium-bearing blast furnace slag, wet titanium extraction, nitric acid leaching, alkali leaching, titanium-rich material