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现代矿业 ›› 2025, Vol. 41 ›› Issue (11): 90-94,99.

• 矿物加工工程 • 上一篇    下一篇

某硫磺热滤渣工艺矿物学研究

邢秉铎1 先永骏1 罗安亮2 张文杰3 冯茜晴1   

  1. 1. 昆明理工大学国土资源工程学院;2. 呼伦贝尔驰宏矿业有限公司;3. 昆明冶金研究院有限公司
  • 出版日期:2025-11-25 发布日期:2025-12-22

Study on Process Mineralogy of Sulfur Thermal Filter Residue

  1. 1. Faculty of Land and Resources Engineering,Kunming University of Science and Technology; 2. Hulun Buir Chihong Mining Co.,Ltd.;3. Kunming Metallurgy Research Institute Co.,Ltd.
  • Online:2025-11-25 Published:2025-12-22

摘要: 为了高效回收内蒙古某硫磺热滤渣中的有价元素,针对其物质组成与赋存状态不 清、矿物嵌布关系复杂等问题,进行了系统的工艺矿物学研究。研究结果表明:该渣中 S、Pb、Zn 和 Ag 的品位分别为 69.94%、4.10%、5.30% 和 172.00 g/t,是具有主要回收价值的元素;其中硫主要以单 质硫的形式存在(占比 80.02%),另有 8.99% 的硫赋存于铜、铅、锌和铁的硫化物中,为次要回收来 源。矿物嵌布特征显示,单质硫多包裹金属硫化矿并与之紧密共生,少部分呈毗连结构;单质硫粒 度较粗(+75 μm 占比 65.69%),而硫化物多为微细-超细嵌布,宜采用阶段磨矿—阶段浮选工艺分别 富集单质硫与金属硫化物。此外,银主要赋存于铅矿物中,其走向应与铅矿物保持一致;鉴于铜、 铅、锌氧化物在金属矿物中占比达 40%~70%,且与主要脉石矿物(石膏、硬石膏)存在差异,可辅以 重选工艺强化此类金属氧化物的回收。

关键词: 硫磺热滤渣, 工艺矿物学, 矿物组成, 粒度

Abstract: In order to efficiently recover valuable elements from a sulfur thermal filter residue in Inner Mongolia,a systematic process mineralogy study is carried out on the problems of unclear material composi⁃ tion and occurrence state,complex mineral dissemination relationship and so on.The results show that the grade of S,Pb,Zn and Ag in the slag is 69.94%,4.10%,5.30% and 172.00 g/t,respectively,which are the main valuable elements for recovery.Among them,sulfur mainly exists in the form of elemental sulfur (80.02%),and 8.99% of sulfur occurs in sulfides of copper,lead,zinc and iron,which is a secondary source of recovery.The characteristics of mineral dissemination show that elemental sulfur is mostly wrapped in metal sulfide ore and closely associated with it,and a small part is adjacent structure. The particle size of elemental sulfur is relatively coarse(+75 μm accounts for 65.69%),while sulfides are mostly fine-ultrafine embedded. It is appropriate to use stage grinding-stage flotation process to enrich elemental sulfur and metal sulfides respectively.In addition,silver mainly occurs in lead minerals,and its direction should be consis⁃ tent with lead minerals. In view of the fact that copper,lead and zinc oxides account for 40%~70% of metal minerals and are different from the main gangue minerals(gypsum and anhydrite),the recovery of such met⁃ al oxides can be strengthened by gravity separation process.

Key words: sulfur thermal filter residue, process mineralogy, mineral composition, particle size