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现代矿业 ›› 2025, Vol. 41 ›› Issue (11): 104-108,113.

• 矿物加工工程 • 上一篇    下一篇

山西尖山铁矿硫赋存状态研究

门业凯1 米子军2 王恩德1 韩良德2   

  1. 1. 东北大学资源与土木工程学院;2. 太原钢铁(集团)有限公司矿业分公司
  • 出版日期:2025-11-25 发布日期:2025-12-22

Study on Sulfur Occurrence State of Jianshan Iron Ores in Shanxi

  1. 1. School of Resources and Civil Engineering,Northeastern University; 2. Mining Branch,Taiyuan Iron and Steel(Group)Co.,Ltd.
  • Online:2025-11-25 Published:2025-12-22

摘要: 尖山铁矿部分批次铁精粉中硫含量过高,不仅严重影响产品质量,还会造成环境污染。 为有效控制铁精粉中的硫含量,采用电子探针、扫描电镜和矿物自动定量分析等手段,对尖山铁矿中 硫的赋存状态和工艺矿物学性质进行了系统的研究。试验结果表明:铁矿石中的硫化物主要呈浸染 状、条带状、细脉状和团块状4种类型,以黄铁矿为主,含少量的黄铜矿和微量的磁黄铁矿;部分硫化 物与磁铁矿物接触共生或包裹共生,选矿流程产品中的含硫矿物绝大部分为黄铁矿,黄铜矿微量,其 他矿物很少;硫化物的单体解离度相对较高,进入到铁精矿产品中的硫化物以单体形式产出为主,与 硫化物连生体嵌连最密切的矿物是磁铁矿,其次是石英、角闪石、绿泥石等;在选矿流程各阶段,精矿 产品中硫化物的解离度呈增大趋势,硫化物与磁铁矿连生比例均较高,呈紧密连生的关系,而与石英 等非金属矿物的比例逐渐降低;表明石英等嵌连矿物可通过选矿流程较好地去除,而对于磁铁矿连 生体则难以有效去除。

关键词: 尖山铁矿, 硫化物, 解离度, 矿物参数, 自动分析系统

Abstract: The high sulfur content in some batches of iron concentrate in Jianshan Iron Mine not only seriously affects the product quality,but also causes environmental pollution. In order to effectively control the sulfur content in iron concentrate powder,the occurrence state and process mineralogical properties of sulfur in Jianshan iron ores are systematically studied by means of electron probe,scanning electron micro⁃ scope and automatic quantitative analysis of minerals.The results show that the sulfides in iron ore are main⁃ ly in four types: disseminated,banded,fine veined and agglomerated,mainly pyrite,with a small amount of chalcopyrite and trace pyrrhotite. Some sulfides are in contact with or enwrapped with magnetite minerals. Most of the sulfur-containing minerals in the beneficiation process products are pyrite,with trace chalcopy⁃ rite and few other minerals. The monomer dissociation degree of sulfides is relatively high,and the sulfides entering the iron concentrate products are mainly produced in the form of monomers. The minerals most closely embedded with sulfides are magnetite,followed by quartz,hornblende,chlorite,etc.In each stage of the beneficiation process,the dissociation degree of sulfide in the concentrate product tends to increase,and the proportion of sulfide and magnetite intergrowth is high,showing a close relationship,while the propor⁃ tion of non-metallic minerals such as quartz gradually decreases. It shows that the embedded minerals such as quartz can be well removed by the beneficiation process,while it is difficult to effectively remove the mag⁃ netite intergrowth.

Key words: Jianshan iron ores, sulfide, dissociation degree, mineral parameters, automatic analysis system