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现代矿业 ›› 2025, Vol. 41 ›› Issue (08): 217-220.

• 安全·环保 • 上一篇    下一篇

硅藻土对多金属选矿废水的吸附试验研究

张京辉 许道刚 龙 冰 卢 斌 刘 杰 郭远发   

  1. 湖南柿竹园有色金属有限责任公司
  • 出版日期:2025-08-25 发布日期:2025-09-29

Experimental Study on Adsorption of Diatomite to Polymetallic Mineral Processing Wastewater

  1. Hunan Shizhuyuan Nonferrous Metals Co.,Ltd.
  • Online:2025-08-25 Published:2025-09-29

摘要: 以湖南柿竹园多金属选矿废水为对象,探讨了硅藻土对废水中COD及重金属锰离子的 吸附效果及机理。通过对比不同吸附剂(活性炭、D401螯合树脂、氧化铝、硅藻土)的处理效果,发现 硅藻土对COD的去除率最高(达60%以上),且对锰离子也有较好吸附能力。进一步进行的吸附条件 优化试验结果表明,硅藻土投加量为7.5 g/L、pH=8、反应时间60 min时效果最佳。动力学分析显示, 硅藻土对COD和锰离子的吸附过程更符合准一级动力学模型,表明其以物理吸附为主。研究证实, 硅藻土作为一种低成本、高效且环保的吸附材料,在多金属选矿废水处理中具有显著的应用潜力,为 实现废水回用提供了可行方案。

关键词: 多金属选矿废水, 硅藻土, 吸附

Abstract: The adsorption effect and mechanism of diatomite on COD and heavy metal manganese ions in wastewater were discussed by taking the multi-metal beneficiation wastewater of Shizhuyuan in Hunan as the object. By comparing the treatment effects of different adsorbents (activated carbon,D401 chelating res‐ in,alumina,diatomite),it was found that diatomite had the highest COD removal rate (more than 60%) and good adsorption capacity for manganese ions. The results of further optimization of adsorption conditions showed that the effect was the best when the diatomite dosage was 7.5 g/L,pH=8 and reaction time was 60 min. The kinetic analysis showed that the adsorption process of COD and manganese ions by diatomite was more in line with the pseudo-first-order kinetic model,indicating that it was mainly physical adsorption. Studies have confirmed that diatomite,as a low-cost,efficient and environmentally friendly adsorption ma‐ terial,has significant application potential in the treatment of multi-metal beneficiation wastewater,and provides a feasible solution for wastewater reuse.

Key words: polymetallic mineral processing wastewater, diatomite, adsorption