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现代矿业 ›› 2025, Vol. 41 ›› Issue (08): 135-139.

• 矿物加工工程 • 上一篇    下一篇

超贫钒钛磁铁矿选铁尾矿资源化利用研究

李柱国1 王 猛1 米宏成2 刘 哲2   

  1. 1. 承德京城矿业集团有限公司;2. 东北大学资源与土木工程学院
  • 出版日期:2025-08-25 发布日期:2025-09-28

Resource Utilization Study of Iron Tailings from Ultra-Lean Vanadium-Titanium Magnetite

  1. 1. Chengde Jingcheng Mining Group Co.,Ltd.; 2. School of Resources and Civil Engineering,Northeastern University
  • Online:2025-08-25 Published:2025-09-28

摘要: 为了实现承德地区某超贫钒钛磁铁矿选铁尾矿的资源化利用,取代表性尾矿样品,进 行了详细的工艺矿物学特性分析以及系统的有价元素回收试验。结果表明,试样中具有回收价值的 元素为磷和钛,P2O5和 TiO2品位分别为 1.52% 和 1.91%,有用矿物为磷灰石、钛铁矿、金红石和榍石。 有用矿物嵌布粒度细、硅酸盐脉石矿物易泥化是影响磷和钛回收的主要因素。在磨矿细度-74 μm占 53% 时,以碳酸钠和 BK116A 为调整剂、BK410B为捕收剂选磷,获得了 P2O5品位为 30.10%、P2O5回收 率为87.61%的磷精矿,然后对选磷尾矿进行湿式弱磁选、湿式强磁选,弱磁粗精矿与强磁粗精矿合并 再磨后经湿式弱磁选和摇床精选,获得了TiO2品位32.10%、TiO2回收率29.66%的钛精矿。研究结果 对该类超贫钒钛磁铁矿尾矿的高效利用具有指导意义。

关键词: 钒钛磁铁矿, 浮选, 磁选, 重选, 资源回收

Abstract: To realize the resource utilization of the iron tailings of an ultra-poor vanadium titanium magnetite in Chengde area,the detailed process mineralogy analysis and systematic recovery of valuable ele‐ ments were carried out by taking representative tailings samples. The results showed that the useful elements were phosphorus and titanium,and the grade of P2O5 and TiO2 were 1.52% and 1.91%,respectively. The valuable minerals include apatite,ilmenite,rutile,and sphene. The fine dissemination size of the valuable minerals and the easy sliming of silicate minerals are the main factors affecting the recovery of phosphorus and titanium. When the grinding fineness is - 74 μm 53%, the phosphate concentrate with P2O5 grade of 30.10% and P2O5 recovery of 87.61% was obtained by using sodium carbonate and BK116A as regulator, BK410B as collector. Then, the phosphate tailings were subjected to wet low intensity magnetic separation, wet high intensity magnetic separation, low intensity magnetic rough concentrate and high intensity magnetic rough concentrate combined and reground, then via wet low intensity magnetic separation and shaking table cleaning, and the ilmenite concentrate with TiO2 grade of 32.10% and TiO2 recovery of 29.66% was obtained. The research results have guiding significance for the efficient utilization of this kind of ultra-poor vanadi‐ um-titanium magnetite tailings.

Key words: vanadium titanium magnetite, flotation, magnetic separation, gravity separation, re‐ source recovery