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Modern Mining ›› 2025, Vol. 41 ›› Issue (12): 207-212.

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Experiment on Clean and Efficient Recovery of Copper from Waste Circuit Boards by Pre-leaching Combined with Cyclone and Vertical Electrodeposition Method#br#

  

  1. College of Environment and Ecology,Hunan Agricultural University
  • Online:2025-12-25 Published:2026-01-26

Abstract: A new method for efficient recovery of copper from waste printed circuit boards (WPCBs) by pre-leaching combined with Cyclone and vertical electrodeposition process was proposed. Firstly,the impurities such as Zn,Fe,Ni and Al in WPCBs were removed by hydrochloric acid pre-leaching. The ef‐ fects of hydrochloric acid concentration,leaching temperature,stirring speed and leaching time on the pre-leaching effect were systematically studied,and the optimum leaching conditions were obtained. The concentration of hydrochloric acid was 1.0 mol/L,the leaching temperature was 35 ℃,the stirring speed was 500 r/min,and the leaching time was 5 min. Under these conditions,the leaching rates of Zn,Fe,Ni and Al reached 99.99%,94.20%,85.10% and 95.20%,respectively. After pre-leaching,the copper con‐ tent in WPCBs was enriched from 38.50% to 60.10%,and the impurity content was significantly reduced. On this basis,Cyclone and vertical electrodepositionwas conducted,the effects of H2SO4 concentration, initial Cu2+ concentration,current density,electrode spacing and liquid-solid ratio on copper recovery and current efficiency were investigated. The optimal electrowinning parameters were obtained as follows. H2SO4 concentration was 180 g/L,initial Cu2+ concentration was 50 g/L,current intensity was 1.5 A,elec‐ trode spacing was 3 cm,and liquid-solid ratio was 50 mL/g. The verification test results show that under the optimal conditions,the copper recovery rate reaches 95.62%,and the purity of cathode copper is high‐ er than 99.9%. The research method provides a feasible process route for the efficient and clean recovery of copper from WPCBs.

Key words: waste printed circuit boards (WPCBs), pre-leaching, cyclone and vertical electrodeposi‐ tion, hydrometallurgy