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现代矿业 ›› 2026, Vol. 42 ›› Issue (07): 123-130,135.

• 矿物加工工程 • 上一篇    下一篇

某选铁尾矿中磷灰石浮选药剂优化试验

赵可可1 李志朝1 王小玉1 丁开振1 程从文1 程 俊1 王 帅2   

  1. 1. 安徽马钢罗河矿业有限责任公司;2. 中钢集团马鞍山矿山研究总院股份有限公司
  • 出版日期:2026-07-25 发布日期:2026-08-03

Optimization Test of Apatite Flotation Reagent in Iron Beneficiation Tailings

ZHAO Keke1 LI Zhichao1 WANG Xiaoyu1 DING Kaizhen1 CHENG Congwen1 CHENG Jun1 WANG Shuai2   

  1. 1. Anhui Masteel Luohe Mining Co.,Ltd.; 2. Sinosteel Maanshan General Institute of Mining Research Co.,Ltd.
  • Online:2026-07-25 Published:2026-08-03

摘要: 某矿山选铁尾矿中 P2O5含量 2.57%,采用强磁选除铁—反浮选脱硫—反浮选脱石 膏—正浮选磷灰石工艺,为解决浮选药剂成本过高的难题,分别探索了脂肪酸的链长、不饱和度及 结构中引入羟基等因素及组合脂肪酸用量、配比对磷灰石、铁白云石和硬石膏浮选的影响。试验 结果表明:当月桂酸钠与油酸钠以质量比 6∶4 进行组合时,磷灰石的可浮性最好;闭路试验在保证 磷精矿 P2O5品位高于 30.00% 及 P2O5回收率超过 40.00% 的前提下,药剂用量降低了 46.15%,捕收剂 药剂成本下降了 34.19%,获得了满意的试验结果。

关键词: 选铁尾矿, 脂肪酸, 磷灰石, 铁白云, 硬石膏, 捕收剂

Abstract: The content of P2O5 in iron beneficiation tailings of a mine is 2.57%. The process of iron removal by high intensity magnetic separation-desulfurization by reverse flotation-degypsum by reverse flo⁃ tation-apatite by direct flotation is adopted.In order to solve the problem of high cost of flotation reagents, the effects of fatty acid chain length,unsaturation,hydroxyl introduced into the structure and the amount and ratio of combined fatty acids on the flotation of apatite,ankerite and anhydrite are explored.The results show that when the mass ratio of sodium laurate to sodium oleate is 6∶4,the floatability of apatite is the best. Under the premise of ensuring that the grade of P2O5 in phosphate concentrate is higher than 30.00% and the recovery rate of P2O5 is more than 40.00%,the dosage of reagent is reduced by 46.15%,and the cost of collector reagent is reduced by 34.19%. Satisfactory test results are obtained.

Key words: iron beneficiation tailings, fatty acid, apatite, iron dolomite, anhydrite, collector