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现代矿业 ›› 2025, Vol. 41 ›› Issue (10): 233-236.

• 实用技术 • 上一篇    下一篇

新型铁尾矿基胶凝材料的制备及充填性能研究

王冬旭 陈洪彬 李万兴 崔志剑   

  1. 鞍钢集团矿业设计研究院有限公司
  • 出版日期:2025-10-25 发布日期:2025-12-08

Research on Preparation and Filling Performance of New Iron Tailings-based Gelling Materials

  1. Ansteel Group Mining Design and Research Institute Co.,Ltd.
  • Online:2025-10-25 Published:2025-12-08

摘要: 铁尾矿富含SiO₂和Al₂O₃,具备潜在的火山灰活性,但常温下活性较低,需通过机械活化或 化学激发可以提升其反应能力。以铁尾矿、水泥熟料、石膏、矿渣微粉等为试验原料制备新型铁尾矿基 胶凝材料。通过正交试验优化配比,确定最优组合为铁尾矿掺量15%、水泥熟料35%、石膏10%、矿渣微 粉为余量(40%),水胶比0.50,验证试验显示试件3,7,28 d抗压强度分别达3.12,7.70,13.94 MPa。进一 步开展冻融循环与水化耐久性试验,结果表明,胶凝材料在标准养护条件下抗冻性良好,但在低温环 境中强度损失显著;长期水浸条件下试块强度略有提升,饱和吸水率介于2.17%~3.11%,表现出良好 的水化稳定性。研究结果为铁尾矿资源化利用与绿色充填材料开发提供了技术支撑。

关键词: 铁尾矿, 胶凝材料, 正交试验, 充填性能

Abstract: Iron tailings are rich in SiO2 and Al2O3,and have potential pozzolanic activity,but the ac⁃ tivity is low at room temperature,and its reactivity can be improved by mechanical activation or chemical ex⁃ citation. A new type of iron tailings-based gelling material was prepared by using iron tailings,cement clin⁃ ker,gypsum and slag powder as test materials. Through the orthogonal test to optimize the ratio,the optimal combination was determined to be 15% iron tailings,35% cement clinker,10% gypsum,slag powder is the residual (40%),and water-binder ratio of 0.50. The verification test showed that the compressive strength of the specimens at 3,7,and 28 d was 3.12,7.70 and 13.94 MPa,respectively. Further freeze-thaw cycle and hydration durability tests were carried out. The results show that the cementitious material has good frost re⁃ sistance under standard curing conditions,but the strength loss is significant in low temperature environ⁃ ment. Under the condition of long-term water immersion,the strength of the test block is slightly improved, and the saturated water absorption rate is between 2.17% and 3.11%,showing good hydration stability. The research results provide technical support for the resource utilization of iron tailings and the development of green filling materials.

Key words: iron tailings, gelling material, orthogonal test, filling performance