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现代矿业 ›› 2025, Vol. 41 ›› Issue (10): 163-169.

• 安全·环保 • 上一篇    下一篇

机械力活化滑石去除废水中铅离子的试验研究

赵晓康1 解素含1 李 钊1 陈 敏2 黄俊玮3 代淑娟1 李鹏程1   

  1. 1. 辽宁科技大学矿业工程学院;2. 辽宁科技大学化学工程学院; 3. 中国地质调查局郑州矿产综合利用研究所
  • 出版日期:2025-10-25 发布日期:2025-12-04

Study on Removal of Lead Ions in Wastewater by Mechanical Activated Talc

  1. 1. School of Mining Engineering,University of Science and Technology Liaoning; 2. School of Chemical Engineering,University of Science and Technology Liaoning; 3. Zhengzhou Institute of Multipurpose Utilization of Mineral Resources,CAGS
  • Online:2025-10-25 Published:2025-12-04

摘要: 为高效去除水溶液中重金属铅离子,对天然黏土矿物滑石进行机械力活化,探究活化 滑石沉淀除铅效果,并对其机理进行分析。研究表明,机械力活化引发滑石晶格畸变,降低其结晶 度,直至完全非晶化。滑石表面活性羟基暴露并溶出,在大气CO₂的共同作用下,与铅离子反应,生成 碱式碳酸铅沉淀。相较于反应活性较低的天然滑石,机械力活化显著提升了矿物理化性质。当球磨 机转速为400 r/min时,滑石用量为0.4 g/L时,机械力活化滑石在500 mg/L硝酸铅溶液中对铅离子的 处理量达到了1 069 mg/g以上。研究结果为黏土矿物资源化利用提供了新途径,并兼具环境修复与 固废再利用双重效益,对推进重金属废水治理的绿色可持续发展具有重要意义。

关键词: 滑石, 机械力活化, 铅离子, 废水处理

Abstract: To efficiently remove heavy metal lead ions from aqueous solutions,mechanical activa⁃ tion was applied to the natural clay mineral talc. The effect of activated talc on precipitating lead ions was explored,and the mechanism was analyzed. The study shows that mechanical activation induces lattice distortion in talc,reducing its crystallinity until complete amorphization. Active hydroxyl groups on the talc surface are exposed and dissolved,reacting with carbon dioxide in the atmosphere to form basic lead carbonate precipitation with lead ions. Compared with natural talc with lower reactivity,mechanical activa⁃ tion significantly enhances the physical and chemical properties of the mineral. When the ball mill speed is 400 r/min and the talc dosage is 0.4 g/L,the treatment capacity of mechanically activated talc for lead ions in a 500 mg/L lead nitrate solution reaches more than 1 069 mg/g. The research results provide a new approach for the resource utilization of clay minerals,and have the dual benefits of environmental remedia⁃ tion and solid waste utilization,which is of great significance for promoting the green and sustainable de⁃ velopment of heavy metal wastewater treatment.

Key words: talc, mechanical activation, lead ions, wastewater treatment