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现代矿业 ›› 2025, Vol. 41 ›› Issue (09): 42-49,61.

• 综合述评 • 上一篇    下一篇

萤石、磷灰石与伴生含钙非金属矿物分选研究进展

纳 瑜1 刘宇墨1 李 钊1 黄俊玮2 陈 敏3 代淑娟1 李鹏程1   

  1. 1. 辽宁科技大学矿业工程学院;2. 中国地质调查局郑州矿产综合利用研究所; 3. 辽宁科技大学化学工程学院
  • 出版日期:2025-09-25 发布日期:2025-11-04

Research Progress on Separation of Fluorite,Apatite and Associated Calcium-containing Non-metallic Minerals

  1. 1. School of Mining Engineering,University of Science and Technology Liaoning; 2. Zhengzhou Institute of Multipurpose Utilization of Mineral Resources,CAGS; 3. School of Chemical Engineering,University of Science and Technology Liaoning
  • Online:2025-09-25 Published:2025-11-04

摘要: 为了缓解萤石、磷灰石等含钙非金属矿产因长期依赖单一型矿石导致的供需矛盾,针 对共伴生型矿石中萤石、磷灰石与方解石、白云石等含钙脉石因表面活性位点相似、矿浆离子交互作 用导致的分选难题,进行了高效分选技术研究。通过分析萤石、磷灰石及其含钙脉石的晶体结构与 表面性质,系统总结了复杂组分差异化分选工艺设计、传统药剂复配改性及新型浮选药剂开发等领 域的研究进展,得出了各类分选技术的适用条件与作用机理,揭示了当前技术瓶颈主要集中于矿物 表面性质调控与药剂选择性吸附方面。未来,应重点发展矿物表面定向修饰技术、智能分选工艺及 环境友好型药剂,为共伴生型含钙非金属矿产资源的高效开发利用提供理论依据与技术方向。

关键词: 含钙矿物, 非金属矿物, 浮选药剂, 工艺流程

Abstract: In order to alleviate the contradiction between supply and demand of calcium-containing non-metallic minerals such as fluorite and apatite due to long-term dependence on a single type of ore, aiming at the separation problems caused by the similarity of surface active sites and the interaction of pulp ions between fluorite,apatite and calcite,dolomite and other calcium-containing gangues in co-associat⁃ ed ores,the efficient separation technology is studied.By analyzing the crystal structure and surface proper⁃ ties of fluorite,apatite and calcium-containing gangue,the research progress in the fields of differential separation process design of complex components,compound modification of traditional reagents and devel⁃ opment of new flotation reagents is systematically summarized. The applicable conditions and mechanism of various separation technologies are obtained,and it is revealed that the current technical bottlenecks main⁃ ly focuses on the regulation of mineral surface properties and selective adsorption of reagents.In the future, it shouldbe focused on the development of mineral surface directional modification technology,intelligent separation technology and environmentally friendly reagents,so as to provide theoretical basis and techni⁃ cal direction for the efficient development and utilization of co-associated calcium-containing non-metallic mineral resources.

Key words: calcium-containing minerals, non-metallic minerals, flotation reagents, process flow