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现代矿业 ›› 2017, Vol. 33 ›› Issue (11): 117-120.

• 矿物加工工程 • 上一篇    下一篇

某氧化铅锌矿浮选试验

饶强坚   

  1. 洋浦华昌矿业有限公司
  • 出版日期:2017-11-25 发布日期:2018-03-01

Flotation Experiment on a Leadzinc Oxide Ore

Rao Qiangjian   

  1. Yangpu Huachang Mining Co.,Ltd.
  • Online:2017-11-25 Published:2018-03-01

摘要:  某低品位氧化铅锌矿石,铅、锌矿物嵌布粒度较细,铅氧化率较高,氧化铅矿石在磨矿过程中容易产生Pb2+,对闪锌矿具有一定的活化作用,增大了铅、锌分离难度。采用硫化工艺,即在球磨机中添加硫化钠,既活化了氧化铅矿石,又减弱了Pb2+对闪锌矿的活化作用。试验以硫酸锌+亚硫酸钠作为锌矿物的抑制剂,25#黑药+丁铵黑药作为铅矿物的捕收剂,实现了对铅矿物的回收;铅浮选尾矿采用抑硫浮锌工艺,以石灰作为黄铁矿的抑制剂,硫酸铜作为闪锌矿活化剂,丁黄作为捕收剂,实现了对锌矿物的回收。最终闭路试验获得的铅精矿含铅66.25%、含锌460%、铅回收率为80.13%;锌精矿含锌57.93%、含铅1.84%、锌回收率为88.77%,试验指标达到了预期效果。

关键词: 氧化铅锌矿,  硫化工艺,  硫酸锌+亚硫酸钠,  25#黑药+丁铵黑药

Abstract: Lead and zinc mineral are finely disseminated in a low grade leadzinc oxide ore. Lead oxidation rate is high, lead oxide minerals in grinding process is easy to produce Pb2+, have certain activation to sphalerite, increases difficult of lead zinc separation. Vulcanization process, namely, adding sodium sulphide in ball mill, not only activated lead oxide ores, but also weakened the Pb2+ activation of sphalerite. Experiment with zinc sulfate and sodium sulfite as inhibitors of zinc mineral, 25# aerofloat and butyl ammonium aerofloat as collector of lead mineral, realize recycling of lead mineral; Lead flotation tailings via sulfur suppression and zinc float technique, with lime as inhibitors of pyrite, copper sulfate as sphalerite activator, xanthate as collector, recovery of zinc mineral was realized. Eventually closed circuit test for lead concentrate has 66.25% Pb, 4.60% Zn, lead recovery rate is 80.13%; zinc concentrate has 57.93% Zn, 1.84% Pb, zinc recovery rate is 88.77%, index has reached expected effect.

Key words: Leadzinc oxide ore, Sulphuration technology, Zinc sulfate and sodium sulfite, 25# aerofloat+butyl ammonium aerofloat